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Wed, May 20

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📄 paper

Perturbative approach to the first law of quantum thermodynamics

In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy contributions whose thermodynamic interpretation is still under debate, raising fundamental questions about the structure of the quantum first law. In this work, we investigate this problem through a time-dependent perturbative framework applied to the first law of quantum thermodynamics. By expanding the thermodynamic quantities up to second order, we derive explicit perturbative corrections for work, heat, and coherence contributions. Our results show that the coherence term can be consistently decomposed into coherent heat and coherent work, demonstrating that quantum coherence does not require the introduction of an independent energetic contribution beyond heat and work. The formalism resolves inconsistencies associated with previous formulations of the quantum first law, including the interpretation of coherence contributions and their connection with entropy fluxes. At second order, the perturbative corrections become directly connected to transition rates governed by Fermi's golden rule, establishing a bridge between microscopic quantum transitions and macroscopic thermodynamic quantities. These results provide a physically transparent framework to investigate coherence-driven thermodynamic processes and offer new perspectives for the analysis of driven quantum systems and nonequilibrium quantum technologies.

Quantum advanced Quantum Physics
By: Mario Reis, Maron F. Anka, Vinicius Gomes de Paula +1 more
Source: arXiv May 19, 2026
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Quantum Algorithms for Nonlinear Differential Equations via Pivot-Shifted Carleman Linearization

We develop a pivot-shifted Carleman linearization framework for quantum algorithms solving quadratic nonlinear ordinary differential equations. By shifting the dynamics by a pivot state prior to Carleman lifting, and combining this with a Lyapunov transform and rescaling, we enlarge the class of nonlinear systems that can be efficiently simulated on quantum computers. For systems that exhibit stability in the shifted coordinates, we establish long time convergence of the truncated Carleman embedding. We prove that the truncation order scales only logarithmically with the simulation time and target precision, and we derive end-to-end quantum query complexity bounds for preparing a state proportional to the final solution. By introducing a modified nonlinearity condition, this framework entirely removes the conventional lower bound requirement on the initial condition. For more general systems that remain unstable after shifting, we provide short time convergence guarantees that are similarly free from the initial condition constraints. Numerical experiments on the logistic and the Lotka-Volterra equations demonstrate that an appropriate pivot choice improves stability and accuracy, and yields exponential error decay with truncation order. These results show that pivot shifting provides a practical and theoretically justified route for extending Carleman-based quantum algorithms to a broader class of nonlinear dynamical systems.

Quantum advanced Quantum Physics
By: Ke Wang, Zikang Jia, Shravan Veerapaneni +1 more
Source: arXiv May 19, 2026
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Ultra-Large-Capacity Passive Quantum Access Network Powered By Single Thermal Source

Quantum Key Distribution (QKD) provides secure keys for classical communications through one-time-pad (OTP) encryption with physical-law security. Advanced PON-based Classical Access Networks (CANs) support up to 256 users with a total rate of 10 Gbps (10-Gbps @ 256-users). The equivalent rate demand of OTP encryption requires QKD Access Networks (QANs) to reach comparable performance, yet state-of-the-art PON-based QANs remain far from this standard. To address this gap, we propose a passive Thermal-State QAN (TS-QAN) distributing polychromatic quantum randomness from a single thermal source and supporting 304 users with an aggregate secret key rate (SKR) of 13 Gbps (13-Gbps @ 304-users). This performance is enabled by three features. First, broadband thermal states with Bose-Einstein statistics can be represented, through the Glauber-Sudarshan representation, as high-bandwidth Gaussian coherent-state ensembles across frequency modes, eliminating many active modulators and quantum random number generators (QRNGs). Second, Electro-Optic (EO) comb beacons provide time-varying polychromatic phase tracking, so each frequency-mode thermal signal can be coherently measured with a Local Local Oscillator (LLO) aided by its beacon, without large-scale phase-locking networks. Third, state broadcasting allows each user to obtain independent final keys via reverse reconciliation after accounting for residual broadcast-induced correlations, expanding network capacity with small SKR losses. Experimentally, we verify a 13-Gbps @ 304-users TS-QAN using Continuous-Variable QKD (CV-QKD) under covariance-matrix-based network security analysis including multimode Holevo leakage and broadcast correlations. This work meets the SKR and capacity demands from CAN to QAN: 13-Gbps @ 304-users satisfies the 10-Gbps @ 256-users benchmark and provides a scalable solution for modern telecommunication systems.

Quantum advanced Quantum Physics
By: Yuehan Xu, Qijun Zhang, Xiaojuan Liao +7 more
Source: arXiv May 19, 2026
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Pauli Correlation Encoding for mRNA Secondary Structure Prediction: Problem-Aware Decoding for Dense-Constraint QUBOs

Pauli Correlation Encoding (PCE) compresses $m$ binary variables onto $n=O(m^{1/k})$ qubits by mapping them to commuting Pauli correlators, but its continuous expectation values must be decoded into feasible binary solutions, a challenge for dense-constraint problems. We apply PCE to mRNA secondary-structure prediction, formulated as a densely constrained QUBO, and train with a QUBO-space sigmoid loss thatpreserves the QUBO penalty structure. For decoding, we introduce the Problem-Aware Guided Decoder (PAGD), which scores candidate variable commitments by combining marginal QUBO energy reduction with a trained expectation-value prior and constraint-aware feasibility pruning. On six benchmark mRNA sequences (30-60 nt, 50-240 variables, 7-14 qubits), PAGD with 100 restarts achieves 75-100 percent near-optimal recovery, defined as $P(\mathrm{gap}<1\%)$, for sequences up to 152 variables, compared with 0-30 percent for a sign-rounding plus local-search baseline. On the 240-variable instance, trained PAGD reaches 50 percent $P(\mathrm{gap}<1\%)$ at 200 restarts, outperforming untrained-circuit and random-expectation-value controls. Hardware-scale tests extend the pipeline to three 102-105 nt instances (694-745 variables, 172,000-193,000 pair constraints, 23 qubits) on IBM Heron processors. The circuits transpile SWAP-free into 480 native two-qubit gates at depth 256, and PAGD decoded gaps on QPU runs match or beat simulator means for all three instances, including exact CPLEX-optimum recovery for one sequence. These results show that PCE-trained priors can survive deployment to noisy superconducting hardware at biologically relevant scale.

Quantum advanced Quantum Physics
By: Triet Friedhoff, Mihir Metkar, Wade Davis +2 more
Source: arXiv May 19, 2026
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Stochastic trajectories and excursions in a double quantum dot system

We investigate the trajectory-level dynamics of a double quantum dot system using the newly developed formalism of stochastic excursions. This approach extends full counting statistics by enabling a filtering of complex trajectories into sub-trajectories, which provide access to the intricate correlations between thermodynamic currents and excursion times. Counting observables are the main object of study in the stochastic excursion framework. Those are defined as a linear combination of transition counts multiplied by their assigned weights within one excursion. For three main counting observables -- charge current, dynamical activity, and entropy production -- we compute averages and noise contributions and show how they provide insights into the operation of the double quantum dot system. At the trajectory level, we analyze outcome distributions for transport and connect the results with trade-offs between successful and unsuccessful events that shape overall performance. We further introduce state observables, which depend on the state visited rather than the transition itself, and discuss the population of the two dots, as well as their correlations. Finally, we discuss thermodynamics of precision through thermo-kinetic uncertainty relations, showing how current precision in different regimes is fundamentally constrained either by entropy production or by dynamical activity. Altogether, our work is a case study that highlights the utility of the excursion framework as a toolkit to analyze many quantities of interest and to uncover the structure of nonequilibrium fluctuations. Moreover, it also suggests new avenues for refining uncertainty relations and understanding transport in mesoscopic systems.

Quantum advanced Quantum Physics
By: Guilherme Fiusa, Pedro E. Harunari, Alberto J. B. Rosal +2 more
Source: arXiv May 19, 2026
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Beyond the Purcell Effect: Controlling Pure Quantum Dephasing with Spin Noise Metasurfaces

One central theme in quantum photonics is tailoring the interactions between atoms/spins and their electromagnetic (EM) environments. Considerable effort has focused on engineering spontaneous emission by shaping EM environments, known as the Purcell effect. However, photonic environment control of pure dephasing, which is a complementary paradigm of non-unitary atom/spin couplings with EM environments, remains largely unexplored. Here, we introduce a nanophotonic approach to modify qubit pure dephasing dynamics. Unlike Purcell engineering that tailors photonic environments at qubit resonance frequencies (typically optical/near-infrared), we develop ultra-subwavelength spin noise metasurfaces for efficient broadband control of low-frequency (e.g., $\sim$MHz) photonic environments far off-resonant with atoms/spins for dephasing engineering. We experimentally demonstrate our approach using lithographically defined CoFeB metasurfaces and shallow nitrogen-vacancy (NV) centers in diamond. Instead of modified spontaneous emission, we observe modified NV pure dephasing dynamics near different spin noise metasurfaces. We further isolate metasurface-controlled dephasing from other dephasing mechanisms (e.g., spin bath) by measuring the NV ensemble dephasing noise spectrum with dynamical decoupling spectral decomposition techniques. Our results establish a new frontier in engineering quantum light-matter interactions with nanophotonic structures.

Quantum advanced Quantum Physics
By: Wenbo Sun, Shoaib Mahmud, Wei Zhang +4 more
Source: arXiv May 19, 2026
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